Texto completo CEPIS/OPS/OMS

PART 414-Organic Chemicals, Plastics, and Synthetic Fibers

Subpart A-General

Sec.
414.10 General definitions.

414.11 Applicability

414.12 Compliance date for pretreatmen stardards for existing sources (PSES).

Subpart B-Rayon Fibers

414.20 Applicability; description of the rayon fibers subcategory.

414.21 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT)

414.22 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology currently available (BCT)

414.23 Effluent limitations representing the degree of effluent reduction attainable by the application of best available technology economically achievable (BAT).

414.24 New source performance srtandards (NSPS).

414.25 Pretreatment standards for existing sources (PSES)

414.26 Pretreatment standards for new sources (PSNS)

Subpart C-Other Fibers

414.30 Applicability; description of the other fibers subcategory.

414.31 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control techology currently available (BPT)

414.32 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional (BCT).[not Reserved]

414.33 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achivable (BAT).

414.34 New source performance srtandards (NSPS).

414.35 Pretreatment standards for new sources (PSES)

414.36 Pretreatment standards for new sources (PSNS)

Subpart D-Thermoplastic Resin

414.40 Applicability; description of the thermoplastic subcategory.

414.41 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).

414.42 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved]

414.43 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT).

414.44 New source performance srtandards (NSPS).

414.45 Pretreatment standards for existing sources (PSES).

414.46 Pretreatment standards for new sources (PSNS).

Subpart E-Thermoplastic Resin

414.50 Applicability; description of the thermosetting resins subcategory.

414.51 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).

414.52 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BPT). [Reserved]

414.53 Effluent limitations representing the degree of effluent reduction

attainable by the application of the best available technology economically achievable (BAT).

414.54 New source performance srtandards (NSPS).

414.55 Pretreatment standards for existing sources (PSES).

414.56 Pretreatment standards for new sources (PSNS).

Subpart F-Commodity Organic Chemicals

414.60 Applicability; description of the comodity organic chemicals subcategory.

414.61 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).

414.62 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved]

414.63 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).

414.64 New source performance srtandards (NSPS).

414.65 Pretreatment standards for new sources (PSNS).

414.66 Pretreatment standards for new sources (PSNS).

Subpart G-Bulk Organic Chemicals

414.70 Applicability; description of the bulgk organic chemicals subcategory.

414.71 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).

414.72 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved].

414.73 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economially achievable (BAT).

414.74 New source performance srtandards (NSPS).

414.75 Pretreatment standards for existing sources (PSES).

414.76 Pretreatment standards for new sources (PSNS).

Subpart H-Bulk Organic Chemicals

414.80 Applicability; description of the specialty organic chemicals subcategory.

414.81 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently availble (BPT).

414.82 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved].

414.83 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT).

414.84 New source performance srtandards (NSPS).

414.85 Pretreatment standards for new sources (PSNS).

Subpart I-Direct Descharge Point Sources That Use End-of-Pipe Biological Treatment

414.90 Applicability; description of the subcategory of direct discharge point sources that do not use end-of-pipe biological treatment.

Subpart J-Direct Descharge Point Sources That Do Not Use End-of-Pipe Biological Treatment

414.100 Applicability; description of the subcategory of direct discharge point sources that do not use end-of-pipe biological treatment.

414.101 Toxic pollutant effluent limitations and standards for direct discharge point sources that do not use end -of-pipe biological treatment.

APPENDIX A TO PART 414-NON COMPLEXED METAL - BEARING WASTE STREAMS AND CYANIDE - BEARING WASTE STREAMS

APPENDIX B TO PART 414-COMPLEXED METAL BEARING WASTE STREAMS.

Authority: Sec. 301, 304, 306, 307, and 501, Pub. L. 92-500, 86 Start. 816, Pub. L. 95-217, 91 Stat. 156, Pub. L. 100-4, 101 Stat. 7 (33 U.S.C. 1311, 1314, 1316, 1317, and 1361).

Source: 52 FR 42568, Nov. 5, 1987, unless otherwise noted.


Subpart A-General

§ 414.10 Direct definitions.
As used in this part:
(a) Except as provided in this regulation, the general definitions, abbreviations, and methods of analysis set forth in part 401 of this chapter shall apply to this part.
(b) Pretreatment control authority means:
(1) The POTW if the POTW's submission for its pretreatment program has been approved in accordance with the requirements of 40 CFR 403.11, or
(2) The Approval Authority if the submission has not been approved.
(c) Priority pollutants means the toxic pollutants listed in 40 CFR 401.15.

§ 414.11 Applicability
(a) The provisions of this part are applicable to process wastewater discharges from all establishments or portions of establishments that manufacture the organic chemicals, plastics, and synthetic fibers (OCPSF) products or product groups covered by subparts B through H of this regulation and are included within the following U.S. Department of Commerce Bureau of the Census Standard Industrial Classification (SIC) major groups:
(1) SIC 2821-Plastic Materials, Synthetic Resins, and Nonvulcanizable Elastomers,
(2) SIC 2823-Cellulosic Man - Made Fibers,
(3) SIC 2824-Synthetic Organic Fibers, Except Cellulosic,
(4) SIC 2865- Cyclic Crudes and Intermediates, Dyes, and Organic Pigments, (5) SIC 2869-Industrial Organic Chemicals Not Elsewhere Classified.
(b) The provisions of this part are applicable to wastewater discharges from OCPSF research and development, pilot plant, technical service and laboratory bench scale operations if such operations are conducted in conjunction with and related to existing OCPSF manufacturing activities at the plant site.
(c) Notwithstanding paragraph (a) of this section, the provisions of this part are not applicable to discharges resulting from the manufacture of OCPSF products if the products are included in the following SIC subgroups and have in the past been reported by the establishment under these subgroups and not under the SIC groups listed in paragraph (a) of this section.
(1) SIC 2843085-bulk surface active agents;
(2) SIC 28914-synthetic resin and rubber adhesives;
(3) Chemicals and Chemical Preparations, not Elsewhere Classified;
(i) SIC 2899568-sizes, all types
(ii) SIC 2899597-other industrial chemical specialties, including fluxes, plastic wood preparations, and embalming fluids;
(4) SIC 2911058-aromatic hydrocarbons manufactured from purchased refinery products; and
(5) SIC 2911632-aliphatic hydrocarbons manufactured from purchased refinery products.
(d) Notwithstanding paragraph (a) of this section, the provisions of this part are not section, applicable to any discharges for which a different set of previously promulgated effluent limitations guidelines and standards in this subchapter apply, unless the facility reports OCPSF products under SIC codes 2865, 2869, or 2821, and the facility's OCPSF wastewaters are treated in a separate treatment system or discharged separately to a publicly owned treatment works.
(e) The provisions of this part do not apply to any process wastewater discharges from the manufacture of organic chemical compounds solely by extraction from plant and animal raw materials or by fermentation processes.
(f) Discharges of chromium, copper, lead, nickel, and zinc in "complexed metal- bearing waste streams," listed in appendix B of this part, are not subject to the requirements of this part.
(g) Nom-amenable cyanide. Discharges of cyanide in "cyanide-bearing waste streams" (listed in Appendix A to this part) are not subject to the cyanide limitations and standards of this part if the permit writer or control authority determines that the cyanide limitations and standards are not achievable due to elevated levels of non-amenable cyanide (i. e., cyanide that is not oxidized by chlorine treatment) that result from the unavoidable complexing of cyanide at the process source of the cyanide-bearing waste stream and establishes an alternatilve total cyanide or amenable cyanide limitation that reflects the best available technology economically achievable. The determination must be based upon a review of relevant engineering, production, and sampling and analysis information, including measurements of both total and amenable cyanide in the waste stream. An analysis of the extent of complexing in the waste stream, based on the foregoing information, and its impact on cyanide treatability shall be set forth in writing and, for direct dischargers, be contained in the fact seet required by 40 CFR 124.8.
(h) Allowances for non-metal-bearing waste streams. Discharge limitations for chromium, copper, lead, nickel, and zinc or discharge standards for lead and zinc may be established for waste streams not listed in Appendix A of this part and not otherwise determined to be "metal-bearing waste streams" if the permit writer or control authority determines that the wastewater metals contamination is due to background levels that are not reasonably avoidable from sources such as intake water corrosion of construction materials or contamination of raw materials. The determination must be based upon a review of relevant plant operating conditions, process chemistry, engineering, and sampling and analysis information. An analysis if the sources and levels of the metals, based on the foregoing information, shall be set forth in writing; for direct dischargers, the analysis shall be set forth in writing; for direct dischargers, the analysis shall be contained in the fact sheet required by 40 CFR 124.8. For direct dischargers, the permit writer may establish limitations for chromium, copper, lead, nickel, and zinc for non-"metal-bearing waste streams" between the lowest level which the permit writer determinates based on best professional judgment can be reliably measured and the concentrations of such metals present in the wastestreams, but not to exceed the applicable limitaions contained in §§414.91 and 414.101. (For zinc, the applicable limitaions which may not be exceeded are those appearing in the tables in §§ 414.91 and 414.101, not the alternative limitations for rayon fiber manufacture by the viscose process and the acrylic fiber manufacture by the zinc chloride/solvent process set forth in footnote 2 to each of these tables.) For indirect dischargers, the control authority may establish standards for lead and zinc for non-"metal-bear-ing waste streams" between the lowest level which the control authority determines based on best professional judgment can be reliably measured and the concentration of such metals present in the wastestreams, but not to exceed the applicable standards contained in §§ 414.25, 414.35, 414.45, 414.55, 414.65, 414.75, and 414.85. (For zinc, the applicable standards which may not be exceeded are those appearing in the tables in the above referenced sections, not the alternative standars for rayon filber manufacture by the viscose process set forth in footnote 2 to the table in §414.25, or the alternative standards for acrylic fiber manufacture by the zinc chloride/solvent process set forth in footnote 2 to the table in §414.35.) The limitations and standards for individual discharges shall be set on a mass basis by multiplying the concentration allowance established by the permit writer or control authority by the process wastewater flow from the individual wastestreams for which incidental metals have been found to be present.
(i) BOD5 and TSS limitations for plants with production in two or more subcategories. Any existing or new source direct discharge point source subject to two or more of subparts B through H must achieve BOD5 and TSS discharges not exceeding the quantity (mass) determined by multiplying the total OCPSF process wastewater flow subject to subparts B through H times the following "OCPSF production-pro-portioned concentration": For a specific plant, let wj. be the proportion of the plant's total OCPSF production in subcategory j. Then the plant-specific production - proportioned concentration limitaions are given by:

H
Plant BOD5 Limit = (SUM(wj)(BOD5 Limitj)
j=B

and

H
Plant TSS Limit= (SUMATORIA(wj)(TSS Limitj)
j=B

The "BOD5 Limitj" and "TSS Limit j" are the respective subcategorical BOD5 and TSS Maximum for Any One Day or Maximum for Monthly Average limitations.

[52 FR 42568, Nov. 5, 1987, as amended at 57 FR 41843, Sept. 11, 1992]

§414.12 Compliance date for Pretreatment Standards for Exising Sources (PSES).
All dischargers subject to PSES in this part must comply with the standads by no later than three years after date of promulgation in the FEDERAl REGISTER.


Subpart B-Rayon Fibers

§ 414.20 Applicability; description of the rayon fibers subcategory.
The provisions of this subart are applicable to process wastewater discharges resulting from the manufacture of rayon fiber by the viscose process only.

§ 414.21 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).
Except as provided in 40 CFR 125.30 through 125.32, and in 40 CFR 414.11 (i) for point sources with production in two or more subcategories, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.

Effluent characteristics BPT Effluent limitations¹
Maximum for any one day Maximum for monthly average
BOD5.....................
TSS......................
pH....................... 		64
130
(2) 		24
40
(2)
1All units except pH are milligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

[52 FR 42568, Nov, 5, 1987, as amended at 57 FR 41844, Sept. 11, 1992]

§ 414.22 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved]

§ 414.23 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technoloogy economically achievable (BAT).
(a) The Agency has d etermined that for existing point sources whose total OCPSF production defined by § 414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for point sources.
(b) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with § 414.91 of this part.
(c) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with § 414.101 of this part.

§ 414.24 New source performance standards (NSPS)
(a) Any source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.91 of this part and also must not exceed the quantity (mass) determined by multiplying to this subpart times the concentrations in the following table.
(b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

Effluent characteristics NSP¹
Maxinum for any one day Maxium for monthly average
BOD5......................
TSS.......................
TpH........................ 		64
130
(2)
 24
40
(2)
1All units except pH are milligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

§ 414.25 Pretreatment standards for existing sources (PSES).
(a) Except as provided in 40 CFR 403.7 and 43.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.
(b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from the cyanide-bearing waste streams for total. The metal-bearing and cynide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-
(1) That such streams contain significant amounts of the pollutants identified above and that
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of relevant engineering, production, and sampling and analysis information.

Effluent characteristics Pretreatment standards¹
Maxinum for any one day Maxium for monthly average
Benzene
Carbon Tetrachloride
Chlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobenzene
1,2-Dichloroethane
1,1,1-Trichloroethane
Hexachloroethane
1,1-Dichloroethane
1,1,2-Trichloroethane
Chloroethane
Chloroform
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethylene
1,2-trans-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methylene Chloride
Methyl Chloride
Hexachlorobutadiene
Nitobenzene
2-Nitrophenol
4-Nitrophenol
4,6-Dinitro-o-cresol
Tetrachloroethylene
Toluene
Trichloroethylene
Vinyl Chloride
Total Cyanide
Total Lead
Total Zinc2
 134
380
380
794
794
574
59
794
59
127
295
325
794
380
380
60
66
794
794
380
170
295
380
6,402
231
576
277
164
74
69
172
1,200
690
2,610
 57
142
142
196
196
180
22
196
22
32
110
111
196
142
142
22
25
196
196
142
36
110
142
2,237
65
162
78
52
28
26
97
420
320
1,050
1All units are micrograms per liter.
2Total Zinc for Ravon Fiber Manufacture that uses the viscose process is 6,796 ug/I and 3,325 ug/I for maximum for any one day and maximum for monthly average, respectively.

[52 FR 42568, Nov, 5, 1987, as amended at 55 FR 26692, June 29, 1990]

Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with §414.111.
[52 FR 36892, July. 9, 1993]

§ 414.26 Pretreatment standards for new sources (PSNS).
(a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quanty (mass determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above § 414.65
(b) In the case of lead, zinc, and total cyanide, the discharge quanty (mass) shall be determined by multiplying the concentrations listed above in §414.65 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on case-by-case basis as metal or cyanide bearing based upon a detemrination-
(1) That such streams contain signigicant amounts of the pollutants identified above and that
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of revelant egineering, production, and sampling and analysis information.
Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with § 411.111.
[58 FR 36892, July 9, 1993]

Subpart C-Other Fibers

§ 414.30 Applicability; description of the other fibers sub-categtory.
The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the following SIC 2865 and 2869 bulk organic chemicals and bulk organic chemical groups. Product groups are indicated with an asterisk (*).
*Acrylic Fibers (85% Polyacrylonitrile)
*Cellulose Acetate Fibers
*Fluorocarbon (Teflon) Fibers
*Modacrylic Fibers
*Nylon 65 Fibers
*Nylon 6 Monofilament
*Nylon 66 Fibers
*Nylon 66 Monofilament
Nylon 66 Monofilament
*Polyamide Fibers (Quiana)
*Polyaramid (Kevlar) Resin-Fibers
*Polyaramid (Nomex) Resin-Fibers
*Polyester Fibers
*Polyethylene Fibers
*Polypropylene Fibers
*Polyurethane Fibers (Spandex)

[52 FR 42568, Nov, 5, 1987, as amended at 57 FR 41844, Sept. 11, 1992]


§ 414.31 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).
Except as provided in 40 CFR 125.30 through 125.32, and in 40 CFR 414.11 (i) for point sources with production in two or more subcategories, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.

Effluent characteristics BPT Effluent limitations1
Maxinum for any one day Maxium for monthly average
BOD5...........
TSS............
pH............... 		48
115
(2) 		18
36
(2)

1All units except pH arf miligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

[52 FR 42568, Nov. 5, 1987, as amended at 57 FR 41844, Sept. 11, 1992]

§414.32 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved]

§414.33 Effluent limitations representing the degree of effluent reduction attainable by the apllication of the best available techonology economically acheivable (BAT).
(a) The Agency has determined that for existing point sources whose total OCPSF production defined by §414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources.
(b) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.91 of this part.
(c) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part.

§414.34 New source performance standards (NSPS)
(a) Any new source that uses end-of-pipe biological treatment an id subject to this subpart must achieve discharges in accordance with §414.91 of quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.
(b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

Effluent characteristics NSPS1 Effluent limitations1
Maxinum for any one day Maxium for monthly average
BOD5...........
TSS............
pH............... 		48
115
(2) 		18
36
(2)

1All units except pH arf miligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

§ 414.35 Pretreatment standards for existing sources (PSES).

(a) Except as provided in 40CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.
(b) In the case of lead, zinc, and total cyanide, the discharge quantity (mass) shall be deteermined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-
(1) That such streams contain significant amounts of the pollutants identified above and that.
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of revelant engineering, production, and sampling and analysis information.

Effluent characteristics Pretreatment standards1
Maxinum for any one day Maximum for monthly average
Benzene
Carbon Tetrachloride
Chlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobenzene
1,2-Dichloroethane
1,1,1-Trichloroethane
Hexachloroethane
1,1-Dichloroethane
1,1,2-Trichloroethane
Chloroethane
Chloroform
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethylene
1,2-trans-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methylene Chloride
Methyl Chloride
Hexachlorobutadiene
Nitobenzene
2-Nitrophenol
4-Nitrophenol
4,6-Dinitro-o-cresol
Tetrachloroethylene
Toluene
Trichloroethylene
Vinyl Chloride
Total Cyanide
Total Lead
Total Zinc2
 134
380
380
794
794
574
59
794
59
127
295
325
794
380
380
60
66
794
794
380
170
295
380
6,402
231
576
277
164
74
69
172
1,200
690
2,610
 57
142
142
196
196
180
22
196
22
32
110
111
196
142
142
22
25
196
196
142
36
110
142
2,237
65
162
78
52
28
26
97
420
320
1,050

1All units are micrograms per liter.

[52 FR 42568, Nov, 5, 1987, as amended at 55 FR 26692, June 29, 1990]

Except as provided in 40 CFR 403.7 and 403.13 ,any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with §411.111.
[58 FR 36892, July 9, 1993]


§ 414.36 Pretreatment standards for new sources (PSNS).
(a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above § 414.35
(b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in §414.35 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater strams identified by the control authority on case-by-case basis as metal or cyanide bearing based upon a detemrination-
(1) That such streams contain signigicant amounts of the pollutants identified above and that.
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of relevant egineering, production, and sampling and analysis information.

Subpart D-Thermoplastic Resins

§ 414.40 Applicability; description of the thermoplastic resin subcategory

The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the products clasified under SIC 28213 thermoplasctic resin including those resin and resin groups listed bellow. Product groups are indicated with an asterisk (*).

*Abietic Acid-Derivatives
*ABS Resins
*ABS-SAN Resins
*Acrylate-Methacrylate Latexes
*Acrylic Latex
*Acrylic Resins
*Cellulose Acetate Butyrates
Cellulose Acetate Resin
*Cellulose Acetates
*Cellulose Acetates Propionates
Cellulose Nitrate
*Ethylene-Methacrylic Acid Copolymers
*Ethylene-Vinyl Acetate Copolymers *Fatty Acid Resins
*Fluorocarbon Polymers
Nylon 11 Resin
*Nylon 6-66 Copolymers
*Nylon 6-Nylon 11 Blends
Nylon 6 Resin
Nylon 612 Resin
Nylon 66 resin
*Nylons
*Petroleum Hydrocarbon Resins
*Polyvinyl Pyrrolidone-Copolymers
*Poly (Alpha) Olefins
Polyacrylic Acid
*Polyamides
*Polyarylamides
Polybutadiene
*Polybutenes
Polybutenyl Succinic Anhydride
*Polycarbonates
*Polyester Resins
*Polyester Resins, Polybutylene Terephthalene
*Polyester Resins, Polyoxybenzoate
Polyethylene
*Polyethylene-Ethyl Acrylate Resins
*Polyethylene-Polyvinyl Acetate Copolymers
Polyethylene Resin (HDPE)
Polyethylene Resin (LPDE)
Polyethylene Resin, Scrap
Polyethylene Resin, Wax (Low M.W.)
Polyethylene Resin, Latex
Polyethylene Resins
*Polyethylene, Resins, Compounded
*Polyethylene, Chlorinated
*Polyimides
*Polypropylene Resins
Polystyrene (Crystal))
Polystyrene (Crystal) Modified
*Polystyrene-Copolymers
*Polystyrene-Acrylic Latexes
Polystyrene Impact Resin
Polystyrene Latex
Polystyrene, Expandable
Polystyrene, Expanded
*Polysulfolne Resins
Polyvinyl Acetate
*Polyvinyl Acetate-PVC Copolymers
*Polyvinyl Acetate Copolymers
*Polyvinyl Acetate Resins
Polyvinyl Acohol Resin
Polyvinil Chloride
Polyvinyl Chloride, Chlorinated
*Polyvinyl Ether-Maleic Anhydride
*Polyvinyl Formal Resins
*Polyvinylacetate-Methacrylic Copolymers
*Polyvinylacetate Acrylic Copolymers
*Polyvinylacetate-2-Ethylhexylacrylate Copolymers
Polyvinylidene Chloride
*Polyvinylidene Chloride Copolymers
*Polyvinylidene-Vinyl Chloride Resins
*PVC Copolymers, Acrylates (Latex)
*PVC Copolymers, Ethylene-Vinyl Chloride
*Rosin Derivative Resins
*Rosin Modified Resins
*Rosin Resins
*SAN Resins
*Silicones: Silicone Resins
*Silicones: Silicones Rubbers
*Styrene Maleic Enhydride Resins
Styrene Polymeric Residue
*Styrene-Acrylic Copolymer Resins
*Styrene-Acrylonitrile-Acrylates Copolymers
*Styrene-Butadiene Resins
*Styrene-Butadiene Resins (<50% Butadiene)
*Styrene-Butadiene Resins (latex)
*Styrene Divinyl Benzene Resins (Ion Exchange)
*Styrene-Methacrylate Terpolymer Resins
*Styrene-Methyl Methacrylate Copolymers
*Styrene, Butadiene, Vinyl Toluene Terpolymers
*Sulfonated Styrene-Maleic Anhydride Resins
*Unsaturated Polyester Resins
*Vinyl Toluene Resins
*Vinyl Toluene-Acrylate Resins
*Vinyl Toluene-Butadiene Resins
*Vinyl Toluene-Methacrylate Resins
*Vinylacetate-N-Butylacrylate Copolymers

[52 FR 42568, Nov, 5, 1987, as amended at 57 FR 41844, Sept. 11, 1992]

§ 414.41 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).
Except as provided in 40 CFR 125.30 through 125.32, and in 40 CFR 414.11 (i) for point sources with production in two or more subcategories, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.

Effluent characteristics BPT Effluent limitations1
Maxinum for any one day Maxium for monthly average
BOD5...........
TSS............
pH............... 		64
130
(2) 		24
40
(2)

1All units except pH arf miligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

[52 FR 42568, Nov. 5, 1987, as amended at 57 FR 41844, Sept. 11, 1992]

§414.42 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved]

§414.43 Effluent limitations representing the degree of effluent reduction attainable by the apllication of the best available techonology economically acheivable (BAT).
(a) The Agency has determined that for existing point sources whose total OCPSF production defined by §414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency isnot promulgating more stringent BAT limitations for these point sources.
(b) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point souce that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.91 of this part.
(c) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part.

§414.44 New source performance standards (NSPS)
(a) Any new source that uses end-of-pipe biological treatment an id subject to this subpart must achieve discharges in accordance with §414.91 of quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.
(b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

Effluent characteristics NSPS1
Maxinum for any one day Maxium for monthly average
BOD5...........
TSS............
pH............... 		64
130
(2) 		24
40
(2)

1All units except pH arf miligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

§ 414.45 Pretreatment standards for existing sources (PSES).
(a) Except as provided in 40CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.
(b) In the case of lead, zinc, and total cyanide, the discharge quantity (mass) shall be deteermined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for total cyanide. The metal-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-
(1) That such streams contain significant amounts of the pollutants identified above and that
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of revelant engineering, production, and sampling and analysis information.

Effluent characteristics Pretreatment standards1
Maxinum for any one day Maximum for monthly average
Benzene
Carbon Tetrachloride
Chlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobenzene
1,2-Dichloroethane
1,1,1-Trichloroethane
Hexachloroethane
1,1-Dichloroethane
1,1,2-Trichloroethane
Chloroethane
Chloroform
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethylene
1,2-trans-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methylene Chloride
Methyl Chloride
Hexachlorobutadiene
Nitobenzene
2-Nitrophenol
4-Nitrophenol
4,6-Dinitro-o-cresol
Tetrachloroethylene
Toluene
Trichloroethylene
Vinyl Chloride
Total Cyanide
Total Lead
Total Zinc2
 134
380
380
794
794
574
59
794
59
127
295
325
794
380
380
60
66
794
794
380
170
295
380
6,402
231
576
277
164
74
69
172
1,200
690
2,610
 57
142
142
196
196
180
22
196
22
32
110
111
196
142
142
22
25
196
196
142
36
110
142
2,237
65
162
78
52
28
26
97
420
320
1,050

1All units are micrograms per liter.

[52 FR 42568, Nov, 5, 1987, as amended at 55 FR 26692, June 29, 1990]

Except as provided in 40 CFR 403.7 and 403.13 ,any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with §411.111.
[58 FR 36892, July 9, 1993]

§ 414.46 Pretreatment standards for new sources (PSNS).
(a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above § 414.35
(b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in §414.35 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater strams identified by the control authority on case-by-case basis as metal or cyanide bearing based upon a detemrination-
(1) That such streams contain signigicant amounts of the pollutants identified above and that
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of revelant egineering, production, and sampling and analysis information.
Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with § 411.111.
[58 FR 36892, July 9, 1993]

Subpart E-Thermosetting Resins

§ 414.50 Applicability; description of the thermoplastic resin subcategory
The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the products clasified under SIC 28213 thermoplasctic resin including those resin and resin groups listed bellow. Product groups are indicated with an asterisk (*).
*Alkyd Resins
Dicyanodinamine Resin
*Epoxy Resins
*Fumaric Acid Polyesters
*Furan Resins
Glyoxal-URea Formaldehyde Textile Resin
*Ketone-Formaldehyde Resins
*Melamine Resins
*Phenolic Resins
*Polyacetal Resins
Polyacrylamide
*Polyurethane Prepolymers
*Polyurethane Resins
*Urea Formaldehyde Resins
*Urea Resins
[52 FR 42568, Nov, 5, 1987, as amended at 57 FR 41884, Sept. 11, 1992]

§ 414.51 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).
Except as provided in 40 CFR 125.30 through 125.32, and in 40 CFR 414.11 (i) for point sources with production in two or more subcategories, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.

Effluent characteristics BPT Effluent limitations1
Maxinum for any one day Maxium for monthly average
BOD5...........
TSS............
pH............... 		163
216
(2) 		61
67
(2)

1All units except pH arf miligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

[52 FR 42568, Nov. 5, 1987, as amended at 57 FR 41844, Sept. 11, 1992]

§414.52 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved]

§414.53 Effluent limitations representing the degree of effluent reduction attainable by the apllication of the best available techonology economically acheivable (BAT).
(a) The Agency has determined that for existing point sources whose total OCPSF production defined by §414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources.
(b) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point souce that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.91 of this part.
(c) Except as provided in paragraph
(a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part.

§414.54 New source performance standards (NSPS)
(a) Any new source that uses end-of-pipe biological treatment an id subject to this subpart must acheive discharges in accordance with §414.91 of quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.
(b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must acheive discharges in accordance with §414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

Effluent characteristics NSPS1
Maxinum for any one day Maxium for monthly average
BOD5...........
TSS............
pH............... 		163
216
(2) 		61
67
(2)

1All units except pH arf miligrams per liter.
2Within the range of 6.0 to 9.0 at all times.

§ 414.55 Pretreatment standards for existing sources (PSES).
(a) Except as provided in 40CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.
(b) In the case of lead, zinc, and total cyanide, the discharge quantity (mass) shall be deteermined by multiplying the concentrations listed in the following table for the metal pollutants times the flow from metal-bearing waste streams for total cyanide. The metal-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination-
(1) That such streams contain significant amounts of the pollutants identified above and that
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of revelant engineering, production, and sampling and analysis information.

Effluent characteristics Pretreatment standards1
Maxinum for any one day Maximum for monthly average
Benzene
Carbon Tetrachloride
Chlorobenzene
1,2,4-Trichlorobenzene
Hexachlorobenzene
1,2-Dichloroethane
1,1,1-Trichloroethane
Hexachloroethane
1,1-Dichloroethane
1,1,2-Trichloroethane
Chloroethane
Chloroform
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethylene
1,2-trans-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methylene Chloride
Methyl Chloride
Hexachlorobutadiene
Nitobenzene
2-Nitrophenol
4-Nitrophenol
4,6-Dinitro-o-cresol
Tetrachloroethylene
Toluene
Trichloroethylene
Vinyl Chloride
Total Cyanide
Total Lead
Total Zinc2
 134
380
380
794
794
574
59
794
59
127
295
325
794
380
380
60
66
794
794
380
170
295
380
6,402
231
576
277
164
74
69
172
1,200
690
2,610
 57
142
142
196
196
180
22
196
22
32
110
111
196
142
142
22
25
196
196
142
36
110
142
2,237
65
162
78
52
28
26
97
420
320
1,050

1All units are micrograms per liter.

[52 FR 42568, Nov, 5, 1987, as amended at 55 FR 26692, June 29, 1990]

Except as provided in 40 CFR 403.7 and 403.13 any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with § 411.111.
[58 FR 36892, July 9, 1993]

§ 414.56 Pretreatment standards for new sources (PSNS).
(a) Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges not exceeding the quantity (mass determined by multiplying the process wastewater flow subject to this subpart times the concentration listed above § 414.45
(b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed above in §414.45 for the metal pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in appendix A of this part, plus any additional process wastewater strams identified by the control authority on case-by-case basis as metal or cyanide bearing based upon a detemrination-
(1) That such streams contain signigicant amounts of the pollutants identified above and that
(2) The combination of such streams, prior to treatment, with the appendix A waste streams will result in substantial reduction of these pollutants.
This determination must be based upon a review of revelant egineering, production, and sampling and analysis information.
Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with § 411.111.

[58 FR 36892, July 9, 1993]

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